I don't know which acronyms you are referring to. However, sorting is basically done by calling the Sort method on your List<T> instance.
The effort on your part is to implement the property interface on your T type (ADODSUser) so that the list can be sorted. You can either implement IComparable(of T) interface or the IComparable interface. Just read the .NET docs to see what you need to do to implement that. It isn't hard and will probably come down to doing string comparisons.
This isn't really a forum for basic .NET programming tasks, so you might need to look to other resources for more info on basic sorting stuff. The MSDN docs are fine here.